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Publication - Professor Nigel Wilding

    Disappearance of the hexatic phase in a binary mixture of hard disks

    Citation

    Russo, J & Wilding, NB, 2017, ‘Disappearance of the hexatic phase in a binary mixture of hard disks’. Physical Review Letters, vol 119.

    Abstract

    Recent studies of melting in hard disks have confirmed the existence of a hexatic phase occurring in a narrow window of density which is separated from the isotropic liquid phase by a first-order transition, and from the solid phase by a continuous transition. However, little is known concerning the melting scenario in mixtures of hard disks. Here we employ tailored Monte Carlo simulations to elucidate the phase behavior of a system of large (l) and small (s) disks with diameter ratio σl/σs=1.4. We find that as small disks are introduced to a system of large ones, the stability window of the hexatic phase shrinks progressively until the line of continuous transitions terminates at an end point beyond which melting becomes a first-order liquid-solid transition. This occurs at surprisingly low concentrations of the small disks, c≤1%, emphasizing the fragility of the hexatic phase. We speculate that the change to the melting scenario is a consequence of strong fractionation effects, the nature of which we elucidate.

    Full details in the University publications repository